What is the 4-Biphenylmethanol?

4-Biphenylmethanol is white to beige powder, while it's Molecular Formula is C13H12O. white to beige powder Biphenyl-4-methanol was used as reagent for the rapid quantitative determination of lithium alkyls.

What is the CAS number for 4-Biphenylmethanol?

The CAS number of 4-Biphenylmethanol is 3597-91-9.

Quality Factory Supply High Purity 99% 4-Biphenylmethanol 3597-91-9 with Fast Shipping

Product Details

Quick Details

CasNo： 3597-91-9
Molecular Formula： C₁₃H₁₂O
Appearance： white to beige powder
Purity： 99%

Quality Factory Supply High Purity 99% 4-Biphenylmethanol 3597-91-9 with Fast Shipping

Molecular Formula:C13H12O
Molecular Weight:184.238
Appearance/Colour:white to beige powder
Vapor Pressure:3.44E-05mmHg at 25°C
Melting Point:96-100 °C(lit.)
Refractive Index:1.595
Boiling Point:340 °C at 760 mmHg
PKA:14.26±0.10(Predicted)
Flash Point:154.9 °C
PSA：20.23000
Density:1.093 g/cm³
LogP:2.84590

4-Biphenylmethanol(Cas 3597-91-9) Usage

Chemical Properties	white to beige powder
Uses	Biphenyl-4-methanol was used as reagent for the rapid quantitative determination of lithium alkyls.
General Description	Biphenyl-4-methanol acts as monofunctional alcohol initiator during the ring-opening polymerization of trimethylene carbonate (TMC) catalyzed by CH3SO3H and copolymerisation of ε-caprolactone and TMC.

InChI:InChI=1/C13H12O/c14-10-11-6-8-13(9-7-11)12-4-2-1-3-5-12/h1-9,14H,10H2

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A new homogeneous polymer support based on syndiotactic polystyrene and its application in palladium-catalyzed Suzuki-Miyaura cross-coupling reactions

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Development of p-phenylbenzyl as a new protecting group: Protection and deprotection of alcohols

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Employing a bifunctional catalyst based ...

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3597-91-9 Process route

: N-benzyl-[1,1′-biphenyl]-4-carboxamide

: 3597-91-9
biphenyl-4-yl methanol

: 100-46-9
benzylamine

Conditions

Conditions	Yield
With sodium 2-methyl-2-adamantoxide; dichlorobis(dicyclohexylphosphinomethylpyridine)-ruthenium (II); hydrogen; sodium hydride; In toluene; mineral oil; at 160 ℃; for 24h; under 45004.5 Torr; Inert atmosphere; Autoclave;	83 %Spectr. 76 %Spectr.
With sodium 2-methyl-2-adamantoxide; C₂₄H₃₈Cl₂N₂P₂Ru; hydrogen; In toluene; at 120 - 160 ℃; for 24h; under 7500.75 - 15001.5 Torr; Autoclave; Sealed tube;	93 %Spectr. 91 %Spectr.

: 139259-95-3
N-(acetyloxy)-N-(([1,1'-biphenyl]-4-ylmethyl)oxy)benzamide

: 3597-91-9
biphenyl-4-yl methanol

: 38418-12-1
[1,1'-biphenyl]-4-ylmethyl benzoate

: 100-52-7
benzaldehyde

: 93-97-0
benzoic acid anhydride

Conditions

Conditions	Yield
With sulfuric acid; water-d2; In [D₃]acetonitrile; at 34.9 ℃; Rate constant; var. conc. of sulfuric acid;	44% 14% 9% 4%

3597-91-9 Upstream products

3218-36-8
4-Phenylbenzaldehyde
50-00-0
formaldehyd
3315-91-1
4-biphenylylmagnesium bromide
349407-14-3
N-methyl-N-phenyl-[1,1'-biphenyl]-4-carboxamide

3597-91-9 Downstream products

1667-11-4
biphenyl-4-methylchloride
644-08-6
4-Methylbiphenyl
126745-85-5
5-(Biphenyl-4-ylmethoxy)-2-phenyl-4-trifluoromethyl-oxazole
128595-03-9
p-phenylbenzyloxycarbonyloxysuccinimide

;

3597-91-9

Quick Details

Quality Factory Supply High Purity 99% 4-Biphenylmethanol 3597-91-9 with Fast Shipping

4-Biphenylmethanol(Cas 3597-91-9) Usage

3597-91-9 Relevant articles

A new homogeneous polymer support based on syndiotactic polystyrene and its application in palladium-catalyzed Suzuki-Miyaura cross-coupling reactions

Shin, Jihoon,Bertoia, Julie,Czerwinski, Kenneth R.,Bae, Chulsung

, p. 1576 - 1580 (2009)

Facile Suzuki-Miyaura cross coupling using ferrocene tethered N-heterocyclic carbene-Pd complex anchored on cellulose

Kale, Dolly,Rashinkar, Gajanan,Kumbhar, Arjun,Salunkhe, Rajashri

, p. 9 - 16 (2017)

Improved aqueous Cannizzaro reaction in presence of cyclodextrin

Canipelle,Landy,Fourmentin

, p. 349 - 353 (2011)

Development of p-phenylbenzyl as a new protecting group: Protection and deprotection of alcohols

Sharma,Rakesh

, p. 5571 - 5573 (2001)

Target alcohol/phenol release by cyclative cleavage using glycine as a safety catch linker.

Raghavan, Sadagopan,Rajender

, p. 1572 - 1573 (2002)

Heterobimetallic Carbene Complexes Bearing Cyclometalated IrIII/RhIII and Mixed NHC∧ Py/PPh3 Coordinated PdII Centers: Structures and Tandem Catalysis

Majumder, Adhir,Nath Saha, Tarak,Majumder, Niladri,Naskar, Rajat,Pal, Kuntal,Maity, Ramananda

, p. 1104 - 1110 (2021)

Assessment of the reusability of Pd complexes supported on fluorous silica gel as catalysts for Suzuki couplings

Tzschucke, Carl Christoph,Andrushko, Vasyl,Bannwarth, Willi

, p. 5248 - 5261 (2005)

Isolation of a metastable geometrical isomer of a hexacoordinated dihydrophosphate: Elucidation of its enhanced reactivity in umpolung of a hydrogen atom of water

Miyake, Hideaki,Kano, Naokazu,Kawashima, Takayuki

, p. 9083 - 9089 (2011)

Novel Transformations of Zaragozic Acid A Derivatives with Cesium Fluoride

Girotra, Narindar N.,Ponpipom, Mitree M.

, p. 2485 - 2488 (1999)

A Bifunctional Copper Catalyst Enables Ester Reduction with H2: Expanding the Reactivity Space of Nucleophilic Copper Hydrides

Kaicharla, Trinadh,Ngoc, Trung Tran,Teichert, Johannes F.,Tzaras, Dimitrios-Ioannis,Zimmermann, Birte M.

supporting information, p. 16865 - 16873 (2021/10/20)

Synthesis of tetranuclear complex of Pd(II) with thiosemicarbazone ligands derived from 2-quinolone and its catalytic evaluation in Suzuki–Miyaura-type coupling reactions and alkoxylation of chloroquinolines

Nandhini, Sundar,Dharani, Sivadasan,Elamathi, Chennakrishnan,Dallemer, Frederic,Prabhakaran, Rathinasabapathi

, (2021/09/06)

Pd(OAc)2-biuret: A highly efficient, low cost and phosphine-free catalyst system for biaryl synthesis under aerobic conditions at room temperature

Saikia, Bishwajit

, (2021/05/10)

New Bidentate N-Sulfonyl-Substituted Aromatic Amines as Chelate Ligand Backbones: Pd Catalyst Generation in C-C Coupling via in Situ and Precatalyst Modes

Oloyede, Hammed Olawale,Akong Akong, Raymond,Woods, Joseph Anthony Orighomisan,G?rls, Helmar,Plass, Winfried,Eseola, Abiodun Omokehinde

, p. 101 - 110 (2020/07/28)

3597-91-9 Process route

3597-91-9 Upstream products

3597-91-9 Downstream products

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